Gerard Moreno of Villarreal opened the scoring in the first half in Wednesday night.
Edinson Cavani equalised early in the second half with his sixth goal in five Europa League games for United.
After a successful 21 penalty kicks David de Gea couldn't save his side giving Villarreal the Europa League at Gdansk Stadium in Poland.
With this win, Villarreal will be heading to Champions League next season.
Unai Emery sets a new landmark for the most UEFA Cup/UEFA Europa League titles as a coach (4) 🏆🏆🏆🏆
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